The quantum mechanical model of the atom (article) | Khan Academy

Introduction to the quantum mechanical model of the atom: Thinking about electrons as probabilistic matter waves using the de Broglie wavelength, the Schrödinger equation, and the Heisenberg uncertainty principle. Electron spin and the Stern-Gerlach experiment.

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Ajouté le

18 mars 2026

Matière et domaine

physics · quantum-mechanics

Niveaux scolaires

10e année (2de)–12e année (Terminale)

Type de page

Article

Introduction

The Quantum Mechanical Model of the Atom

  • Wave-Particle Duality: Louis de Broglie proposed that all particles exhibit wave-like properties, characterized by a specific wavelength.
  • Schrödinger’s Model: Erwin Schrödinger developed the quantum mechanical model, treating electrons as matter waves. His wave equation yields wave functions ($\psi$) associated with specific electron binding energies ($E$).
  • Probability Density: The square of the wave function ($\psi^2$) represents the probability of locating an electron in a specific region of the atom.
  • Atomic Orbitals: Defined as the region within an atom where an electron is likely to be found 90% of the time.
  • Heisenberg Uncertainty Principle: It is impossible to simultaneously know both the precise position and energy (momentum) of an electron; increasing precision in one decreases precision in the other.
  • Electron Spin: Electrons possess an intrinsic property called spin, which can be either "spin-up" or "spin-down."
  • Pauli Exclusion Principle: Any two electrons occupying the same orbital must have opposite spins.
  • Fermions vs. Bosons: Electrons are classified as fermions (possessing fractional spin), whereas force-carrying particles are bosons (possessing integer spin).
  • Key Experimental Context: The Stern-Gerlach experiment is central to understanding electron spin, utilizing non-uniform magnetic fields to observe particle deflection.

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